VMXNET 3: Supported Guest Operating Systems

VMXNET 3 is the newest NIC driver for VMs (requries VM HW v7). It should be chosen as default for all supported guest operating systems. Windows Server 2000, however, is not supported. Here's link to VMware KB with more info. Remember, that when you delete the old NIC and add a new one, then all IP info is wiped and should be reconfigured (mostly relevant for static IPs).